Rezumat
CZU 620.197
The corrosion of copper – nickel alloy in hydrochloric acid has been investigated at different temperatures, benzotrizole concentrations and corrosive solution velocities. Weight loss technique has been used to evaluate the corrosion rate data. Results obtained have proved that benzotrizole has a dual effect by reducing both metal corrosion and flow losses. Maximum inhibition efficiency was 91.5%, while maximum drag reduction was 52.4%. Several mathematical equations are suggested successfully to represent the data with high correlation coefficients. Molecular dynamic simulations have been also performed to investigate the adsorption behavior of the inhibitor on the copper alloy surface. One of the novelties of the given work is the analogy between the corrosion process and fluid flow, as well as the investigation of the dual effect of benzotriazole on the corrosion process and the flow losses.
Keywords: fluid flow, weight loss, rotating disc electrode, acid corrosion, drag reduction.