Size Effect of the Rate of Deposition of Со-W Coatings from a Citrate Electrolyte

Abstract

UDC 541.138.2

 

DOI https://doi.org/10.52577/eom.2022.58.6.37

 

It is shown that during the electrodeposition of Co-W coatings from a citrate electrolyte two types of size effects of the process rate (dependence of the electrodeposition rate on the surface dimensions) can be observed: a microeffect due to the influence of microelectrode sizes on the diffusion current density and a macroscopic size effect associated with the structure of the cobalt complex.

 

Keywords: induced co-deposition, cobalt-tungsten alloy, size effects in electrochemistry.

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