Anti-Corrosion Coatings on SS 304 by Incorporation of Pr₆O₁₁-TiO₂ in Siloxane Network

Abstract

UDC 621.373.826

This paper describes an attempt to develop anticorrosive siloxane coatings based on Pr₆O₁₁-TiO₂ composite films for SS 304 substrate by sol-gel technique. We demonstrate for the use of praseodymium oxide doped Titanium oxide (Pr₆O₁₁-TiO₂) nanocomposites loaded in a hybrid sol-gel layer, to effectively protect the underlying steel substrate from corrosion attack. The influence of Pr₆O₁₁-TiO₂ gives the surprising aspects based on active anti-corrosion coatings. The silica sol was treated with Pr₆O₁₁-TiO₂ to achieve different level of add-on i.e.) 0–1 wt% of nanocomposites. The influence of different weight percent of nanocomposites on silica matrix for anticorrosion performance was investigated by Electrochemical Impedance Spectroscopy (EIS). Pr₆O₁₁-TiO₂ nanocomposites loaded in a hybrid sol-gel layer effectively protect the underlying substrate from corrosion attack. The results showed significant improvement in anticorrosion property for higher add-ons up to the optimized percent of nanocomposites. Furthermore, Transmission Electron Microscopy (TEM) and Scanning Electron Microscope Microscopy (SEM) were used to characterize the surface morphology of doped and undoped coatings. The studied showed a synergistic effect between Pr₆O₁₁-TiO₂ and siloxane matrix has leads to a self-healing coatings.

Keywords: sol-gel process, anticorrosion, nanocomposites, EIS.