https://eom.usm.md/index.php/journal/issue/feed ELEKTRONNAYA OBRABOTKA MATERIALOV 2025-07-02T17:39:46+03:00 Tatiana D. Shemyakova seae.journal@gmail.com Open Journal Systems <p>ELEKTRONNAYA OBRABOTKA MATERIALOV</p> <p>(Electronic Processing of Materials)</p> <p>EOM/EPM is a non-profit scientific journal that publishes open access articles under the <a href="https://creativecommons.org/licenses/by/4.0/">Creative Commons License Creative Commons Attribution 4.0 International License</a>.</p> <p>The journal accepts original papers containing the results of research and reviews on topical areas of theoretical foundations and practical applications of electroerosive and electrochemical methods of processing materials, physicochemical methods of obtaining macro-, micro- and nanomaterials, studies of their properties, electrical processes in technology, chemistry, in the processing of biological and food objects, electromagnetic fields in biosystems.</p> <p>Frequency of publications – 6 issues per year.</p> <p>Some of the articles from the journal „Elektronnaya obrabotka materialov” are translated into English and published in the USA as “Surface Engineering and Applied Electrochemistry” by the publisher Allerton Press, Inc./Pleiades Publishing and distributed by the company Springer. The web addresses of the English version of the journal : <a href="https://www.pleiades.online/en/journal/surfeng">https://www.pleiades.online/en/journal/surfeng</a> ; <a href="https://www.springer.com/journal/11987">https://www.springer.com/journal/11987</a>.</p> https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.01 Increasing of Wear Resistance of Heat-Resistant Nickel Alloy Using Anodic Plasma Electrolytic Treatment 2025-07-02T14:45:55+03:00 Grigoriev S.N. a@b.c Mukhacheva T.L. a@b.c Tambovsky I.V. a@b.c Kusmanova I.A. a@b.c Sorokina O.V. a@b.c Gaponov V.A. a@b.c Mustafaev E.S. a@b.c Suminov I.V. a@b.c Kusmanov S.A. a@b.c <p><strong>UDC</strong> 544.558+66.088</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.01">https://doi.org/10.52577/eom.2025.61.3.01</a></p> <p>&nbsp;</p> <p style="text-align: justify;">A possibility of the plasma electrolytic treatment of a heat-resistant nickel alloy ChN77TiAlB, which leads to the removal of edge cracks, a decrease in hardness and an increase in wear resistance, is shown. The volt-ampere and volt-temperature characteristics of the plasma electrolytic treatment, typical for anodic processes, are revealed. Changes in the morphology and roughness of the surface, the structure and microhardness of the surface layers are considered. It was established that the treatment in an electrolyte based on carbamide and ammonium chloride leads to the formation of nitrocarburized layers without the formation of compounds. The combined effect of both high-temperature oxidation and anodic dissolution on the morphology and roughness of the surface was determined. Tribological tests were conducted using the ball-on-disk scheme, which showed the best results after treatment at 900 °C (reduction in volumetric wear by 15.7 times), when a reduction in roughness (by 5 times) and the presence of thick oxide layers determine a uniform running-in period, reaching a lower value of the friction coefficient, and homogenization of the alloy, accompanied by the removal of cracks, determines a softer wear mechanism. Positive results were obtained in abrasive wear tests: after treatment at 600 and 900 °C, volumetric wear decreased by 2.6 and 2.2 times, respectively.</p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><em>Keywords:</em> heat-resistant nickel alloy, plasma electrolytic treatment, microhardness, surface roughness, wear resistance, friction coefficient.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.12 Structure, Mechanical and Corrosion Properties of Coatings Based on ZrN Solid Solution 2025-07-02T16:29:35+03:00 Cherenda N.N. a@b.c Grigor’ev S.N. a@b.c Basalai A.V. a@b.c Bibik N.V. a@b.c Vereshchaka A.A. a@b.c Izobello A.Yu. a@b.c Reva O.V. a@b.c Rusal’skii D.P. a@b.c Kuleshov A.K. a@b.c Uglov V.V. a@b.c Bagaev S.I. a@b.c <p><strong>UDC</strong> 67.017</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.12">https://doi.org/10.52577/eom.2025.61.3.12</a></p> <p>&nbsp;</p> <p style="text-align: justify;">The structure, elemental composition, mechanical and corrosion properties of (Zr, Nb)N, (Zr, Hf)N and (Zr, Nb, Hf)N vacuum-arc coatings deposited on the titanium alloy Ti-6Al-4V were studied. The X-ray diffraction analysis, scanning electron microscopy, microhardness measurement, adhesion and corrosion tests were used as investigation techniques. It was found that the coatings were single-phase solid solutions based on ZrN. The highest microhardness value (17 GPa) was observed for the (Zr, Hf, Nb)N coating, and the lowest value (9 GPa) – for the (Zr, Nb)N coating. The (Zr, Hf)N coating also possessed the highest critical force Lc3 during scratch tests. Comparison with the data obtained earlier showed that a decrease of the Nb concentration in the (Zr, Nb)N coating and an increase of the Hf concentration in the (Zr, Hf)N coating led to the growth of the critical force Lc3. Corrosion tests carried out in a 3% NaCl solution in the galvanostatic mode showed that the (Zr, Nb)N coating maintained continuity over the entire surface of the alloy in contrast to the coatings containing Hf atoms.</p> <p style="text-align: justify;">&nbsp;</p> <p><em>Keywords:</em> titanium alloy, biomedical implants, nitride coatings, adhesion, microhardness, corrosion.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.24 Electrochemical and Corrosion Behavior of Ni-Re Alloys and Their Components 2025-07-02T16:52:52+03:00 Parshutin V.V. a@b.c Paramonov A.M. a@b.c Koval’ A.V. a@b.c <p><strong>UDC</strong> 621.9.047.7:669.018.8</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.24">https://doi.org/10.52577/eom.2025.61.3.24</a></p> <p>&nbsp;</p> <p style="text-align: justify;">The comparative corrosion resistance and electrochemical behavior of the deformed and annealed Ni-Re alloys and their components in acidic, alkaline, and neutral media was investigated. Nickel alloying with rhenium leads to sharp strengthening of the solid solution both in the deformed and in the annealed state. However, at the same time, the corrosion resistance of an alloy in 48% H<sub>2</sub>SO<sub>4</sub> decreases, but increases in the concentrated HCl and HNO<sub>3</sub>. The diffusive-migration nature of limiting current of alloys at anode polarization in NaCl solutions was established (as well as at dissolution of Ni and Co). The deformed metals are less resistant than annealed ones in all media.</p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><em>Keywords:</em> corrosion resistance, nickel-rhenium alloys, deformed alloy, annealed alloy, tests in aggressive media.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.38 Effect of Gamma Irradiation on the Electrophysical Parameters of Nickel-Doped Silicon Grown by the Czochralski Method 2025-07-02T17:04:23+03:00 Iliev Kh.M. a@b.c Ismailov K.A. a@b.c Kosbergenov E.Zh. a@b.c Odzhaev V.B. a@b.c Prosolovich V.S. a@b.c Yankovskii Yu.N. a@b.c Kenzhaev Z.T. a@b.c Isakov B.O. a@b.c Kushiev G.A. a@b.c <p><strong>UDC</strong> 621.315.592</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.38">https://doi.org/10.52577/eom.2025.61.3.38</a></p> <p>&nbsp;</p> <p style="text-align: justify;">The effect of γ-irradiation on the electrophysical parameters of silicon doped with nickel during growth from melt according to the Czochralski method was studied. Experimental results obtained by the scanning electron microscopy showed that clusters of Ni atoms ~ 6÷8 μm in size with a surface density of ~ (5÷8) × 10<sup>3</sup> cm<sup>-2</sup> were formed in nickel-doped silicon during cultivation. It was established that during irradiation with γ-quanta <sup>60</sup>Co of the control samples not doped with nickel, material compensation occurs due to the generation of deep centers of radiation origin. In silicon samples doped with nickel, when irradiated with γ-quanta, the size of the clusters decreased, and the concentration of free charge carriers changed slightly: when the fluence increased to Ф ≥ 3∙10<sup>8</sup> rad, and the resistivity decreased by no more than 30%. Such a change in the parameters of Si &lt; Ni &gt; samples is due to the formation of acceptor centers because of an increase in the concentration of electrically active nickel atoms. It was shown that during irradiation nickel atoms diffuse from clusters into the silicon matrix, where upon interaction with radiation-generated vacancies interstitial nickel atoms Ni<sub>i</sub> pass into electrically active position in the Ni<sub>s</sub> crystal lattice unit. Those impurity defect centers (Ni<sub>s</sub>) were thermally stable to at least an annealing temperature of 600 °C.</p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><em>Keywords:</em> γ-irradiation, clusters, nickel, doping, silicon.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.45 Methodology for Designing an Ultrasonic System for Thermosonic Wire Ball Bonder 2025-07-02T17:17:30+03:00 Petukhov I.B. a@b.c Lanin V.L. a@b.c <p><strong>UDC</strong> 621.791.16</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.45">https://doi.org/10.52577/eom.2025.61.3.45</a></p> <p>&nbsp;</p> <p style="text-align: justify;">A methodology for designing an ultrasonic system is proposed, which provides the stability of thermosonic gold wire bonding with a diameter of 17.5–50 μm during the assembly of electronics devices in cermet. Modeling of the waveguide was carried out at the standard frequency of ultrasound of 66 kHz and an increased frequency of 136 kHz.</p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><em>Keywords:</em> wire bonding, cermet circuit packaging, ultrasonic/thermosonic micro bonding, ultrasonic transducer, transducer horn, sound speed, bonding capillary.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.52 Control of Electron Localization in Pentameric Nanoclusters of Various Configurations in an External Electric Field 2025-07-02T17:24:44+03:00 Yaltychenko O.V. a@b.c Kanarovskii E.Yu. a@b.c <p><strong>UDC</strong> 538.9+539.1.01+539.189</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.52">https://doi.org/10.52577/eom.2025.61.3.52</a></p> <p>&nbsp;</p> <p style="text-align: justify;">A minimal theoretical model for describing the dynamics of localization of a shared electron in a pentamer nanocluster in an external low-frequency electric field, taking into account the electron-vibrational interaction, is proposed. Based on the given model, the system of differential equations was obtained regarding the time dependences of amplitudes of the probability of finding an electron on different centers of a pentamer. This model was used to describe the pentamers of linear and square-planar configurations. For those two types of the pentamer configuration, the numerical calculations were performed at different values of model parameters. The proposed model is characterized by the fact that the centers of the nanocluster are considered as weakly tunnel-coupled, and the electron-vibrational coupling with the ligand environment on each of its centers plays a significant role. Moreover, tunneling is taken into account only between the nearest centers of the nanocluster while the cluster centers are considered equivalent. The control role of an external electric field was revealed so that the variations of its amplitude and frequency allowed to realize the various electron localization regimes in the pentamer nanocluster. By setting up the values of those electric field parameters, the duration of the full localization of an electron at a certain cluster center (or centers) was regulated, as well as the rate of switching the localization of an electron to another cluster center (or centers), and the overall distribution of electron density in the nanocluster.</p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><em>Keywords:</em> pentamer nanocluster, ligand environment, electron-vibrational interaction, low-frequency electric field, electron localization.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV https://eom.usm.md/index.php/journal/article/view/eom.2025.61.3.61 Synchronization and Symmetrization of the Main Voltages of Transformer-Based Power Electronic Converters in the Overmodulation Zone of Voltage Source Inverters 2025-07-02T17:31:57+03:00 Oleschuk V.I. a@b.c <p><strong>UDC</strong> 621.314.572</p> <p>DOI&nbsp; <a href="https://doi.org/10.52577/eom.2025.61.3.61">https://doi.org/10.52577/eom.2025.61.3.61</a></p> <p>&nbsp;</p> <p style="text-align: justify;">This article discusses the features of the synchronous regulation of inverter blocks of two topologies of the transformer-based photovoltaic installations based on two and three three-phase voltage source inverters operating in a specific over-modulation zone characterized by increased, close to maximum values, modulation indices of inverters. It is shown that, in the case of a two-range inverter control strategy in the over-modulation mode, the modified algorithms of a synchronous pulse-width modulation, including the use of specialized correction coefficients for each sub-range of the over-modulation zone, allowed for the continuous synchronization and symmetry of the basic voltage waveforms on the inverter-side windings of the power transformer of photovoltaic systems throughout the entire inverter over-modulation zone. The results of modeling the processes in the systems confirm the fact of the absence of harmonic components of even-order and subharmonics (of the fundamental frequency of photovoltaic stations) in the spectra of the basic voltages of the analyzed photovoltaic installations over the entire range of two-stage regulation of inverters in the over-modulation zone. Such an improvement in the harmonic composition of the basic voltages leads to a decrease in losses and an increase in the efficiency of the functioning of photovoltaic installations based on inverters with synchronous modulation, which is especially important for high-power systems characterized by a relatively low switching frequency of the power switches of the inverters.</p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><em>Keywords:</em> three-phase voltage inverter, synchronous pulse-width modulation, photoconverter installation, multi-winding power transformer, harmonic composition of voltage.</p> 2025-07-02T00:00:00+03:00 Copyright (c) 2025 ELEKTRONNAYA OBRABOTKA MATERIALOV