О ПРЕДЕЛЬНОЙ СКОРОСТИ РАЗМЕРНОГО ЭЛЕКТРООСАЖДЕНИЯ ПРИ ПОЛУЧЕНИИ МЕЗО- И НАНОМАТЕРИАЛОВ В УСЛОВИЯХ ТЕМПЛАТНОГО СИНТЕЗА

Аннотация

It was shown correlation between the rates of ionic mass transfer limiting the rate of silver electrode- position from rodanide and copper from pyrophosphate electrolytes and the limiting rate of dimentional electrodeposition of this metals into nanopores 100-200 nm of size at conditions of template synthesis. It has been determined that the thicknesses of deposited layers at fixing values of passed charge may be increased by pulse electrodeposition and by electrodeposition in atmosphere of inert gas. It was shown that limitations of control of electrodeposition rates possibilities by pulse electrodeposition are depended by corrosion metal in the time off.

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